Does order matter in Marvel?

Hello, I got Marvel Unlimited and want to read some stuff. The thing is that I have no idea where to start. I hear a lot of good stuff about The Immortal Hulk for example but I can I just start right there?

My fave heroes are:

Wolverine Black Panther Hulk Iron Man Spiderman Captain America Avengers in general

Does it matter where you start with these or can you just pick the latest?

And how do I fgure out where to start?

Thank you in advance!